有机化学实验 英-汉双语版 第2版【2025|PDF|Epub|mobi|kindle电子书版本百度云盘下载】

有机化学实验 英-汉双语版 第2版PDF格式电子书版下载

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Part 1 Introduction1

1.1 General Rules for the Organic Chemistry Lab1

1.2 General Lab Safety2

1.3 Disposal of Lab Waste3

1.4 Common Lab Equipment and Apparatus4

1.5 Drying and Drying Agent12

1.6 Heating and Cooling13

1.7 Experimental Record and Laboratory Report14

1.8 Chemical Literature15

Part 2 Basic Experimental Techniques18

2.1 Melting Point18

2.2 Recrystallization22

2.3 Simple Distillation and Fractional Distillation27

2.4 Steam Distillation31

2.5 Vacuum Distillation34

2.6 Solvent Extraction and Solution Washing38

2.7 Sublimation43

2.8 Refractive Index of Liquids45

2.9 Optical Rotation48

2.10 Chromatographic Techniques50

2.11 Spectroscopic Identification of Organic Compound63

Part 3 Experiments73

3.1 Preparation of Cyclohexene73

3.2 Preparation of n-Butyl Bromide75

3.3 Preparation of Triphenylmethanol78

3.4 Preparation of Dibutyl Ether82

3.5 Preparation of Benzoic Acid and Benzyl Alcohol85

3.6 Preparation of Cyclohexanone88

3.7 Preparation of Adipic Acid91

3.8 Preparation and Characterization of Cinnamic Acid93

3.9 Preparation of Acetylsalicylic Acid(Aspirin)96

3.10 Preparation of n-Butyl Acetate98

3.11 Preparation of n-Dibutyl Phthalate101

3.12 Preparation of Acetanilide103

3.13 Isolation of Caffeine From Tea Leaves107

3.14 Preparation of 2-Furanmethanol and 2-Furoic Acid110

3.15 Preparation of 8-Quinolinol113

Part 4 All-around Experiments115

4.1 Synthesis and Characterization of Ethyl Acetate and Ethyl Acetoacetate115

4.2 Synthesis of Sulfanilic Acid and Methyl Orange120

4.3 Coenzyme Preparation and Characterization of Benzoin125

4.4 Preparation and Characterization of Benzilic Acid128

4.5 Microwave-Assisted Preparation and Characterization of 2-Substitutedphenylbenzoxazole130

Part 5 Experiments from Literature132

5.1 A Microscale Synthesis of the Diastereomers of 2,3-Dibromosuccinic Acid132

5.2 A Grignard-like Organic Reaction in Water134

5.3 An Efficient Microscale Procedure for the Synthesis of Aspirin134

5.4 A Solvent-Free Claisen Condensation Reaction135

5.5 The Preparation of a Fluorescent Dye:A Microscale TLC Experiment135

5.6 Microwave Microscale Experiment——2-Naphthyl Acetate from 2-Naphthol136

Part 6 Appendix137

6.1 List of the Element with Their Symbols and Atomic Masses137

6.2 Main Families of Organic Compounds140

第一部分　有机化学实验的一般知识141

1.1　有机化学实验的基本规则141

1.2　有机化学实验的一般安全知识141

1.3　有机化学实验废物的处置142

1.4　常用的玻璃仪器和实验装置143

1.5　干燥与干燥剂144

1.6　加热与冷却145

1.7　实验记录和实验报告146

1.8　有机化学的文献资料146

第二部分　基本操作148

2.1　熔点的测定148

2.2　重结晶150

2.3　蒸馏与分馏151

2.4　水蒸气蒸馏153

2.5　减压蒸馏154

2.6　萃取与洗涤156

2.7　升华158

2.8　液体化合物折光率的测定158

2.9　旋光度的测定160

2.10　色谱技术161

2.11　有机化合物的光谱鉴定166

第三部分　有机化合物的制备172

3.1　环己烯的制备172

3.2　1-溴丁烷的制备173

3.3　三苯甲醇的制备175

3.4　正丁醚的制备178

3.5　苯甲酸和苯甲醇的制备179

3.6　环己酮的制备180

3.7　己二酸的制备182

3.8　肉桂酸的制备及结构表征183

3.9　乙酰水杨酸（阿司匹林）的制备185

3.10　乙酸正丁酯的制备186

3.11　邻苯二甲酸二正丁酯的制备187

3.12　乙酰苯胺的制备188

3.13　从茶叶中提取咖啡因190

3.14　呋喃甲醇和呋喃甲酸的制备192

3.15　8-羟基喹啉的制备193

第四部分　综合性实验196

4.1 乙酸乙酯和乙酰乙酸乙酯的制备和结构表征196

4.2　对氨基苯磺酸和甲基橙的制备198

4.3　辅酶催化安息香的制备及结构表征201

4.4　二苯基乙醇酸的制备及结构表征203

4.5　2-取代苯基苯并噁唑的微波法合成205

第五部分　文献实验206

5.1　非对映体的2,3-二溴琥珀酸的微量合成206

5.2　在水相中进行的类似格利雅反应207

5.3　微量法合成阿司匹林207

5.4　无溶剂的Claisen缩合反应208

5.5　一种荧光染料的制备：微量TLC实验208

5.6　微波法微量实验：2-萘酚制备乙酸-2-萘酯209

第六部分　附录210

6.1　与化学有关的INTERNET网址210

6.2　有机化学实验（上）操作考试复习题211

6.3　有机化学实验（下）操作考试复习题213